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In the potential energy diagram of a molecule, the activation energy is the energy that is


A) necessary to get the molecule to form.
B) above the ground state of the molecule.
C) released when the molecule is formed.
D) stored in the molecule.
E) at the ground state of the molecule.

F) A) and E)
G) All of the above

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A diatomic quantum mechanical rotator in the L = 1 quantum state has energy E. The same rotator in the L = 2 quantum state will have energy


A) 2E.
B) 3E.
C) 6E.
D) 8E.
E) none of the given answers

F) A) and D)
G) A) and E)

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Silver has a Fermi level of 5.5 eV. At 0 K, what is the speed of the electrons with the Fermi speed?


A) 1.4 × 106 m/s
B) 1100 m/s
C) 2200 m/s
D) 0
E) 1.1 × 106 m/s

F) A) and B)
G) C) and D)

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Which of the following statements is true?


A) In a p-type doped semiconductor the donor level is close to the valence band.
B) In an n-type doped semiconductor the acceptor level is close to the valence band.
C) In a p-type doped semiconductor the acceptor level is close to the valence band.
D) In an n-type doped semiconductor the donor level is close to the valence band.
E) None of the statements are true.

F) B) and E)
G) B) and C)

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The conductivity of a semiconductor sharply increases when 400 nm (or shorter) wavelength light is shone upon it. This is consistent with what energy gap for this material?


A) 3.6 eV
B) 0.45 eV
C) 2.0 eV
D) 3.1 eV
E) 1.0 eV

F) C) and D)
G) None of the above

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When a p-n junction diode is forward biased


A) a current does not flow through it.
B) a current flows through it from the p-side to the n-side.
C) a current flows through it from the n-side to the p-side.
D) a current flows because holes and electrons are traveling in opposite directions away from the junction.
E) a current flows because holes and electrons are traveling in the same direction towards the junction.

F) A) and B)
G) D) and E)

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An unfilled electron state in the valence band is called


A) a hole.
B) an empty electron.
C) a conduction electron.
D) a positron.
E) an empty positron.

F) C) and D)
G) A) and E)

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A diatomic quantum mechanical oscillator has a moment of inertia of 7.73 × 10-45 kg∙m2. What is the rotational energy in the quantum state characterized by L = 2?


A) 2.27 × 10-5 eV
B) 2.72 × 10-5 eV
C) 5.87 × 10-5 eV
D) 7.22 × 10-5 eV
E) 8.71 × 10-5 eV

F) B) and E)
G) A) and C)

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If the potential energy diagram, when shown as a function of the separation of the atoms in the molecule, has a positive slope, then the force between the atoms


A) has the highest possible value.
B) is attractive.
C) has the lowest possible value.
D) is repulsive.
E) is none of the above.

F) A) and B)
G) C) and D)

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The bond energy for a hydrogen molecule is


A) 1.5 eV.
B) 2.5 eV.
C) 3.5 eV.
D) 4.5 eV.
E) 5.5 eV.

F) C) and E)
G) A) and B)

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For a diatomic quantum mechanical rotator, the energy difference between adjacent energy levels


A) increases as L increases.
B) decreases as L increases.
C) is constant for all L.
D) varies randomly as L increases.

E) All of the above
F) B) and C)

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For a diatomic quantum mechanical vibrator, the energy difference between adjacent quantum states


A) increases as v increases.
B) decreases as v increases.
C) is constant for all values of v.
D) varies randomly as v increases.

E) C) and D)
F) A) and C)

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Van der Waals bonding is caused by


A) the sharing of electrons between atoms.
B) the transfer of electrons between atoms.
C) unequal charge distribution around neutral molecules.
D) atoms bonding to hydrogen molecules.
E) atoms bonding to oxygen molecules.

F) C) and D)
G) A) and D)

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The spacing of the atoms in the H2 molecule is 7.4 x 10-11 m. What is the moment of inertia of this molecule about its center of mass?


A) 1.5 x 10-47 kg∙ m2
B) 1.9 x 10-47 kg∙ m2
C) 9.1 x 10-48 kg∙ m2
D) 4.6 x 10-48 kg∙ m2
E) 2.3 x 10-48 kg∙v

F) A) and E)
G) B) and D)

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A p-type semiconductor has a net positive charge.

A) True
B) False

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An n-type semiconductor is produced by


A) doping the host crystal with donor impurities.
B) doping the host crystal with accepter impurities.
C) pure crystals of germanium.
D) all of the above.
E) none of the above.

F) A) and B)
G) B) and D)

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