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A block of dry ice (solid CO2, density = 1.56 g/mL) of dimensions 25.0 cm × 25.0 cm × 25.0 cm is left to sublime (i.e., to pass from the solid phase to the gas phase) in a closed chamber of dimensions 4.00 m × 5.00 m × 3.00 m.Once the sublimation is complete, what is the partial pressure of carbon dioxide in the chamber at 25°C? (R = 0.08206 L • atm/K • mol, 1 atm = 760 mmHg)


A) 172 mmHg
B) 107 mmHg
C) 0.225 mmHg
D) 0.172 mmHg
E) 14.4 mmHg

F) B) and D)
G) B) and C)

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Determine the partial pressure of CO2 in a gas mixture composed of 782.4 grams of CO2 and 2.10 moles of CO.The mixture is at 703.3 K in a 25.8-liter container.


A) 4.70 atm
B) 44.5 atm
C) 39.8 atm
D) 22.4 atm
E) 17.8 atm

F) B) and C)
G) C) and D)

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A 0.271-g sample of an unknown vapor occupies 294 mL at 140°C and 847 mmHg.The empirical formula of the compound is CH2.What is the molecular formula of the compound? (R = 0.08206 L • atm/K • mol)


A) CH2
B) C2H4
C) C3H6
D) C4H8
E) C6H12

F) B) and D)
G) A) and E)

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A gaseous compound is 30.4% nitrogen and 69.6% oxygen by mass.A 5.25-g sample of the gas occupies a volume of 1.00 L and exerts a pressure of 1.26 atm at −4.0°C.What is its molecular formula? (R = 0.08206 L • atm/K • mol)


A) NO
B) NO2
C) N3O6
D) N2O4
E) N2O5

F) A) and D)
G) A) and E)

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A sample of hydrogen gas exerts a pressure of 466 torr in a container.What is this pressure in atmospheres? (1 atm = 1.01325 ×105 Pa = 760 torr)


A) 0.217 atm
B) 0.466 atm
C) 0.613 atm
D) 1.63 atm
E) 4.60 atm

F) A) and D)
G) D) and E)

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What is the final temperature of a gas that expands from a volume of 22.4 L at 278 K to a volume of 38.3 L?


A) 163 K
B) 294 K
C) 3.09 K
D) 217 K
E) 475 K

F) A) and B)
G) A) and E)

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What is the density of CO2(g) at 100.°C and 10.0 atm pressure? (R = 0.08206 L • atm/K • mol)


A) 1.44 g/L
B) 134 g/L
C) 44.0 g/L
D) 53.6 g/L
E) 14.4 g/L

F) B) and E)
G) B) and D)

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E

What is the volume occupied by 35.2 g of methane gas (CH4) at 25°C and 1.0 atm? (R = 0.08206 L • atm/K • mol)


A) 0.0186 L
B) 4.5 L
C) 11.2 L
D) 49.2 L
E) 53.7 L

F) B) and C)
G) C) and D)

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E

"The pressure of an ideal gas is inversely proportional to its volume at constant temperature and number of moles" is a statement of __________________ law.


A) Charles's
B) Boyle's
C) Amontons's
D) Avogadro's
E) Gay-Lussac's

F) All of the above
G) A) and B)

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"The volume of an ideal gas is directly proportional to the number of moles of the gas at constant temperature and pressure" is a statement of _____________ law.


A) Charles's
B) Boyle's
C) Dalton's
D) Avogadro's
E) Gay-Lussac's

F) None of the above
G) B) and E)

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D

A flask with a volume of 3.16 L contains 9.33 g of an unknown gas at 32.0°C and 1.00 atm.What is the molar mass of the gas? (R = 0.08206 L • atm/K • mol)


A) 7.76 g/mol
B) 66.1 g/mol
C) 73.9 g/mol
D) 81.4 g/mol
E) 144 g/mol

F) A) and C)
G) C) and E)

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If the atmospheric pressure in Denver is 0.8800 atm, what is this pressure expressed in mmHg? (1 atm = 101,325 Pa = 760 torr, 1 torr = 1 mmHg) ?


A) 151.5 mmHg
B) 1.16× 10−3 mmHg
C) 863.6 mmHg
D) 8.92 × 104 mmHg
E) 668.8 mmHg

F) None of the above
G) A) and B)

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A sample of nitrogen gas at 298 K and 745 torr has a volume of 37.42 L.What volume will it occupy if the pressure is increased to 894 torr at constant temperature?


A) 22.3 L
B) 31.2 L
C) 44.9 L
D) 112 L
E) 380 L

F) B) and E)
G) A) and E)

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If 2.3 mol of a gas occupies 50.5 mL, how many moles of the gas will occupy 85.5 mL at the same temperature and pressure?


A) 1.4 mol
B) 0.59 mol
C) 3.9 mol
D) 0.26 mol
E) 2.3 mol

F) A) and E)
G) A) and D)

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Which figure best represents the concept of pressure? (A sphere represents a gaseous atom.)


A) Which figure best represents the concept of pressure? (A sphere represents a gaseous atom.)  A)    B)    C)    D)
B) Which figure best represents the concept of pressure? (A sphere represents a gaseous atom.)  A)    B)    C)    D)
C) Which figure best represents the concept of pressure? (A sphere represents a gaseous atom.)  A)    B)    C)    D)
D) Which figure best represents the concept of pressure? (A sphere represents a gaseous atom.)  A)    B)    C)    D)

E) C) and D)
F) A) and C)

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What is the mass, in grams, of 2.74 L of CO gas measured at 33°C and 945 mmHg? (R = 0.08206 L • atm/mol • K, 1 atm = 760 mmHg)


A) 0.263 g
B) 2.46 g
C) 3.80 g
D) 35.2 g
E) 206 g

F) C) and D)
G) B) and C)

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What is the density of SF6(g) at 27°C and 0.500 atm pressure? (R = 0.08206 L • atm/K • mol)


A) 3.38 × 10−3 g/L
B) 2.97 g/L
C) 22.4 g/L
D) 32.9 g/L
E) 3.38 kg/L

F) None of the above
G) A) and E)

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Determine the mole fraction of CO in a gas mixture composed of 782.4 grams of CO2 and 2.10 moles of CO.The mixture is at 703.3 K in a 25.8-liter container.


A) 0.11
B) 0.89
C) 17.8
D) 0.48
E) 0.52

F) None of the above
G) C) and E)

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The air pressure in a volleyball is 75 psi.What is this pressure in torr? (1 atm = 14.7 psi = 101,325 Pa = 760 torr) ?


A) 520 torr
B) 562 torr
C) 3900 torr
D) 7600 torr
E) 75,000 torr

F) C) and D)
G) A) and B)

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A 7.75-L flask contains 0.482 g of hydrogen gas and 4.98 g of oxygen gas at 65°C.What is the partial pressure of oxygen in the flask?


A) 0.557 atm
B) 0.043 atm
C) 1.11 atm
D) 33.5 atm
E) 67 atm

F) D) and E)
G) A) and B)

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